Hide Your Online Status From Selected Friends:
So you want to use Facebook chat but don’t want some people to see your
online status?
Simply open up the Facebook Chat and click on Friends List. Start creating a
new list
called BlockList.
Once the list is created, add those friends to the list that you want to appear
offline to. When the list is complete, hover your mouse to the little green icon
adjacent to the list and click Go Offline. Bingo! You will now appear offline to
everybody in the BlockList.